Regioselective iron-catalyzed allylic amination

Research output: Contribution to journal › Research article › Contributed › peer-review

Contributors

  • Bernd Plietker - , Dortmund University of Technology (Author)

Abstract

(Chemical Equation Presented) Iron age: An air- and water-resistant iron(-II) catalyst, in the presence of triphenylphosphane under buffered conditions, allows for the highly regioselective and stereoselective allylation of primary aromatic amines. A broad substrate range both in the aniline and in the allyl carbonate moiety is tolerated.

Details

Original languageEnglish
Pages (from-to)6053-6056
Number of pages4
JournalAngewandte Chemie - International Edition
Volume45
Issue number36
Publication statusPublished - 11 Sept 2006
Peer-reviewedYes
Externally publishedYes

External IDs

ORCID /0000-0001-8423-6173/work/142250841

Keywords

ASJC Scopus subject areas

Keywords

  • Allylic amination, Arylamines, Homogeneous catalysis, Iron, Regioselectivity

Library keywords