Redox-active, porous pyrene tetraone dendritic polymers as cathode materials for lithium-ion batteries

Research output: Contribution to journal › Research article › Contributed › peer-review

Contributors

  • Lucas Ueberricke - , Heidelberg University  (Author)
  • Felix Mildner - , Heidelberg University  (Author)
  • Yuquan Wu - , Heidelberg University  (Author)
  • Elisa Thauer - , Heidelberg University  (Author)
  • Tom Wickenhäuser - , Heidelberg University  (Author)
  • Wen Shan Zhang - , Heidelberg University  (Author)
  • Yana Vaynzof - , Center for Advancing Electronics Dresden (cfaed), Chair of Emerging Electronic Technologies (gB/IFW) (Fak. EuI), Heidelberg University  (Author)
  • Sven M. Elbert - , Heidelberg University  (Author)
  • Rasmus R. Schröder - , Heidelberg University  (Author)
  • Rüdiger Klingeler - , Heidelberg University  (Author)
  • Michael Mastalerz - , Heidelberg University  (Author)

Abstract

Redox active, insoluble pyrene tetraone based dendritic porous polymers were synthesized by using different catalyst loadings and work-up procedures. The dendritic polymers were investigated by gas sorption analysis for their porosity and characterized with respect to their properties as active material in cathodes of lithium ion secondary batteries. Electrochemical measurements by means of cyclic voltammetry and galvanostatic cycling show reversible redox activity and specific capacities of up to 137 mA h g−1 with a capacity retention of 86% after 50 cycles.

Details

Original languageEnglish
Pages (from-to)1604-1611
Number of pages8
JournalMaterials Advances
Volume4
Issue number6
Publication statusPublished - 2 Mar 2023
Peer-reviewedYes

External IDs

WOS 000945514600001

Keywords

Sustainable Development Goals

ASJC Scopus subject areas

Keywords

  • Covalent organic framework, Density-functional theory, Energy-storage, Radical polymers, Pore systems, Performance, Electrodes, Catalysts, Devices

Library keywords