Record-high thermal barrier of the relaxation of magnetization in the nitride clusterfullerene Dy2ScN@C80-IhI  h

Research output: Contribution to journal › Research article › Contributed › peer-review

Contributors

  • D. S. Krylov - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • F. Liu - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • S. M. Avdoshenko - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • L. Spree - , Faculty of Physics, Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • B. Weise - , Chair of Metallic Materials and Metal Physics, Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • A. Waske - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • A. U.B. Wolter - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • B. Büchner - , Chair of Experimental Solid State Physics, Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • A. A. Popov - , Leibniz Institute for Solid State and Materials Research Dresden (Author)

Abstract

The Dy-Sc nitride clusterfullerene Dy2ScN@C80-Ih exhibits slow relaxation of magnetization up to 76 K. Above 60 K, thermally-activated relaxation proceeds via the fifth-excited Kramers doublet with the energy of 1735 ± 21 K, which is the highest barrier ever reported for dinuclear lanthanide single molecule magnets.

Details

Original languageEnglish
Pages (from-to)7901-7904
Number of pages4
JournalChemical communications
Volume53
Issue number56
Publication statusPublished - 2017
Peer-reviewedYes

External IDs

PubMed 28656179

Keywords

ASJC Scopus subject areas