Rearrangement of the orbital-ordered state at the metal-insulator transition of La7/8Sr1/8MnO3

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • J. Geck - , RWTH Aachen University, Max Planck Institute for Intelligent Systems (Author)
  • P. Wochner - , Max Planck Institute for Intelligent Systems (Author)
  • D. Bruns - , German Electron Synchrotron (DESY) (Author)
  • B. Büchner - , German Electron Synchrotron (DESY) (Author)
  • U. Gebhardt - , Max Planck Institute for Intelligent Systems (Author)
  • S. Kiele - , RWTH Aachen University, German Electron Synchrotron (DESY) (Author)
  • P. Reutler - , RWTH Aachen University, French National Centre for Scientific Research (CNRS) (Author)
  • A. Revcolevschi - , French National Centre for Scientific Research (CNRS) (Author)

Abstract

We present a resonant x-ray scattering study at the manganese K edge on La7/8Sr1/8MnO3 at temperatures between 10 K and 310 K along with thermal expansion, magnetization, and electrical resistivity measurements. At the Mn K edge the symmetry-forbidden (300) reflection is observed in the whole temperature range under investigation and its integrated intensity is found to be directly connected to structural distortions. In particular, the intensity of the (300) reflection increases strongly in the cooperative Jahn-Teller distorted phase between 150 K and 270 K. The increase of the resonant intensity in this temperature regime, the rotation of the beam polarization from σ to π, the sin2-azimuthal dependence and the anomalies displayed by the lattice constants give firm experimental evidence for an orbital ordered state between 150 K and 270 K similar to that found in LaMnO3. Upon cooling, the intensity of the (300) reflection collapses at the charge ordering temperature TCO=150K and the resonant (1.5,1.5,3) superstructure reflection emerges. This reflection also displays a resonant behavior at the Mn K edge and a pronounced azimuthal dependence. However, a resonant signal is observed in the σσ as well as in the σπ channel. The results reveal that the metal-insulator transition of La7/8Sr1/8MnO3 is accompanied by an orbital reordering.

Details

Original languageEnglish
JournalPhysical Review B - Condensed Matter and Materials Physics
Volume69
Issue number10
Publication statusPublished - 19 Mar 2004
Peer-reviewedYes
Externally publishedYes

External IDs

ORCID /0000-0002-2438-0672/work/158767798