Polypeptide-shelled poly(propylene imine) dendrimers and their complexing properties towards copper(II) ions
Research output: Contribution to journal › Research article › Contributed › peer-review
Contributors
Abstract
Polypeptide-shelled poly(ptopylene imine) dendrimers were realized by ring-opening polymerization of α-amino acid N-carboxyanhydrides, initiated by dendrimers as core molecules. Polypeptides with 2nd generation core were used as model compounds to investigate interior complexes between metal ion and surface-modified dendrimers. Microcalorimetric measurements outlined the formation of approximate 1:1 complexes between CuII and polypeptide-shelled dendrimers and the influence of polypeptide chain compositions on differential molar heats of complexation.
Details
Original language | English |
---|---|
Pages (from-to) | 586-591 |
Number of pages | 6 |
Journal | Macromolecular rapid communications |
Volume | 26 |
Issue number | 8 |
Publication status | Published - 22 Apr 2005 |
Peer-reviewed | Yes |
External IDs
WOS | 000228797700002 |
---|---|
ORCID | /0000-0002-4531-691X/work/148607731 |
Keywords
ASJC Scopus subject areas
Keywords
- Complexation, Dendrimers, Peptides, Thermodynamic properties