Polyesters with bio-based ferulic acid units: crosslinking paves the way to property consolidation

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • Doris Pospiech - , Leibniz Institute of Polymer Research Dresden (Author)
  • Andreas Korwitz - , Leibniz Institute of Polymer Research Dresden (Author)
  • Hartmut Komber - , Leibniz Institute of Polymer Research Dresden (Author)
  • Dieter Jehnichen - , Leibniz Institute of Polymer Research Dresden (Author)
  • Kerstin Arnhold - , Leibniz Institute of Polymer Research Dresden (Author)
  • Harald Brunig - , Leibniz Institute of Polymer Research Dresden (Author)
  • Holger Scheibner - , Leibniz Institute of Polymer Research Dresden (Author)
  • Michael T. Mueller - , Leibniz Institute of Polymer Research Dresden (Author)
  • Brigitte Voit - , Chair of Organic Chemistry of Polymers, Leibniz Institute of Polymer Research Dresden, TUD Dresden University of Technology (Author)

Abstract

Aromatic-aliphatic polyesters can be prepared as bio-based materials by incorporating monomers from biogenic sources. Here, 2-methyl (E)-3-(4-(2-hydroxyethoxy)-3-methoxyphenyl)acrylate, a derivative of ferulic acid, was synthesised and inserted into the structure of aliphatic and aromatic-aliphatic polyesters as a comonomer. Terpolymers with high relative molar masses M-w from 50 000 to 100 000 g mol(-1) can be successfully prepared by transesterification polycondensation in the melt. Incorporation of ferulate units with intact double bonds is proven by NMR spectroscopy. Insertion of low molar amounts of ferulate units reduces the crystallinity of the base polyesters, but enhances the glass transition temperature. It is demonstrated that the materials after melt processing to a suitable shape (fibres, parts, films) can be crosslinked by electron beam irradiation, which enhances the stability of the materials.

Details

Original languageGerman
Pages (from-to)5139-5148
Number of pages10
JournalPolymer chemistry
Volume12
Issue number36
Early online dateAug 2021
Publication statusPublished - 21 Sept 2021
Peer-reviewedYes

External IDs

Scopus 85115990899
ORCID /0000-0002-4531-691X/work/148608021

Keywords

Keywords

  • Lignin, Polymers, Vanillin, Degradation, Fuels