Phase-formation maps of CuZrAlCo metallic glass explored by in situ ultrafast techniques

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • Xiaoliang Han - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • Ivan Kaban - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • Jiri Orava - , Leibniz Institute for Solid State and Materials Research Dresden, Jan Evangelista Purkyne University in Usti nad Labem (Author)
  • Qi Cheng - , CAS - Institute of Physics (Author)
  • Yong Hao Sun - , CAS - Institute of Physics (Author)
  • Ivan Soldatov - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • Martin v. Zimmermann - , German Electron Synchrotron (DESY) (Author)
  • Kaikai Song - , Shandong University (Author)
  • Kornelius Nielsch - , Chair of Metallic Materials and Metal Physics, Leibniz Institute for Solid State and Materials Research Dresden (Author)

Abstract

Crystallization of Cu47.5Zr48Al4Co0.5 metallic glass upon isokinetic and isothermal annealing is studied by conventional and ultrafast differential scanning calorimetry, resistive flash-annealing, and in situ high-energy X-ray diffraction. The fast-heating experiments of Cu47.5Zr48Al4Co0.5 metallic glass are complemented by in situ high-energy XRD studies of the undercooled liquid by using electromagnetic levitation. The combination of complementary techniques reveals a competition between the Cu10Zr7, B2 CuZr and τ4 Cu2ZrAl phases crystallization depending on heating rate and shows the specific role of Co alloying. A continuous-heating-transformation diagram for a heating rate exceeding six orders of magnitude, Φ = 0.0833 − 90 000 K s−1, and a time-temperature-transformation diagram are constructed.

Details

Original languageEnglish
Article number118371
JournalActa materialia
Volume241
Publication statusPublished - Dec 2022
Peer-reviewedYes

Keywords

Keywords

  • Crystallization, Electromagnetic levitation, Flash DSC, Flash-annealing, Metallic glass, Phase transformations, Solidification, Synchrotron X-ray diffraction