Optimal control of a molecular cis-trans isomerization model

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • TUD Dresden University of Technology

Abstract

The dynamics of a laser-driven nuclear wave packet on two coupled potential energy surfaces with 2 degrees of freedom, modeling the torsion of a C-C double bond interacting with a vibrational mode, is studied by numerically solving the time-dependent Schrodinger equation. An optimal control scheme is employed to determine the laser field to realize a nano-switch for cis-trans isomerization. The basic mechanism of the controlled isomerization process as well as the features of the optimal laser field and its dependence on the final time chosen for the optimization are studied in detail.

Details

Original languageEnglish
Pages (from-to)201-206
Number of pages6
JournalEurophysics letters
Volume60
Issue number2
Publication statusPublished - Oct 2002
Peer-reviewedYes

External IDs

Scopus 0036798505

Keywords

Keywords

  • QUANTUM-OPTIMAL-CONTROL, PHOTOISOMERIZATION, DYNAMICS