Optimal control of a molecular cis-trans isomerization model
Research output: Contribution to journal › Research article › Contributed › peer-review
Contributors
- TUD Dresden University of Technology
Abstract
The dynamics of a laser-driven nuclear wave packet on two coupled potential energy surfaces with 2 degrees of freedom, modeling the torsion of a C-C double bond interacting with a vibrational mode, is studied by numerically solving the time-dependent Schrodinger equation. An optimal control scheme is employed to determine the laser field to realize a nano-switch for cis-trans isomerization. The basic mechanism of the controlled isomerization process as well as the features of the optimal laser field and its dependence on the final time chosen for the optimization are studied in detail.
Details
Original language | English |
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Pages (from-to) | 201-206 |
Number of pages | 6 |
Journal | Europhysics letters |
Volume | 60 |
Issue number | 2 |
Publication status | Published - Oct 2002 |
Peer-reviewed | Yes |
External IDs
Scopus | 0036798505 |
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Keywords
Keywords
- QUANTUM-OPTIMAL-CONTROL, PHOTOISOMERIZATION, DYNAMICS