Optical properties of MoOCl2: Anisotropic plasma frequencies, effective masses, and interband excitations

Research output: Contribution to journal › Research article › Contributed › peer-review

Contributors

  • Maryam Rezvani Amin - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • Marco Naumann - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • Falk Röder - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • Bernd Büchner - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • Martin Knupfer - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • Xianjie Liu - , Linköping University (Author)
  • Jinpeng Yang - , Yangzhou University (Author)
  • Xu Gao - , Soochow University (Author)
  • Bo Xu - , China Pharmaceutical University (Author)

Abstract

MoOCl2 is a metallic, layered van der Waals material with a strong in-plane structural anisotropy. The reflectivity of a MoOCl2 single crystal has been determined in a wide spectral range from the infrared to the visible regime. This reflectivity is extremely anisotropic, reflecting the anisotropic crystal structure and electronic properties of MoOCl2. Using a Drude–Lorentz fit, we extracted the dielectric function quantitatively for the two in-plane directions of MoOCl2, and we determined the anisotropic optical effective mass of the conduction electrons. Our data additionally demonstrate the presence of interband excitations in the measured spectral range.

Details

Original languageEnglish
Article number175120
JournalPhysical Review B
Volume114
Issue number17
Publication statusPublished - Sept 2026
Peer-reviewedYes
Externally publishedYes