Occupancy disorder in the magnetic topological insulator candidate Mn1-x Sb2+x Te4

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • Laura C. Folkers - , Junior Professorship in Synthesis and Crystal Growth of Quantum Materials, Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • Laura Teresa Corredor - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • Fabian Lukas - , Leibniz Institute for Solid State and Materials Research Dresden, TUD Dresden University of Technology (Author)
  • Manaswini Sahoo - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • Anja U.B. Wolter - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • Anna Isaeva - , Leibniz Institute for Solid State and Materials Research Dresden, University of Amsterdam (Author)

Abstract

MnSb2Te4 is a candidate magnetic topological insulator exhibiting more pronounced cation intermixing than its predecessor MnBi2Te4. Investigating the cation intermixing and its possible implications on the magnetic order in MnSb2Te4 are currently hot topics in research on quantum materials for spintronics and energy-saving applications. Two single-crystal X-ray diffraction measurements of Mn1-x Sb2+x Te4 (x = 0.06 and x =-0.1) are presented alongside a detailed discussion of its crystal structure with a spotlight on the apparent occupancy disorder between the two cations. This disorder has been noted by other groups as well, yet never been analyzed in-depth with single-crystal X-ray diffraction. The latter is the tool of choice to receive a meaningful quantification of antisite disorder. Between the two synthesis procedures we find subtle differences in phases and/or alternation of the cation content which has implications on the magnetic order, as illustrated by bulk magnetometry. Understanding and assessing this disorder in magnetic topological insulators of the MnX2Te4 (X = Bi, Sb) type is crucial to gauge their applicability for modern spintronics. Furthermore, it opens new ways to tune the "chemical composition-physical property"relationship in these compounds, creating an alluring aspect also for fundamental science.

Details

Original languageEnglish
Pages (from-to)101-108
Number of pages8
JournalZeitschrift fur Kristallographie - Crystalline Materials
Volume237
Issue number4-5
Publication statusPublished - 1 May 2022
Peer-reviewedYes

Keywords

Keywords

  • magnetic topological materials, magnetism, single crystal X-ray diffraction, site disorder