Noncollinear antiferromagnetism of coupled spins and pseudospins in the double perovskite La2CuIrO6

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • Kaustuv Manna - , Max Planck Institute for Gravitational Physics (Albert Einstein Institute) (Author)
  • R. Sarkar - , TUD Dresden University of Technology (Author)
  • S. Fuchs - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • Y. A. Onykiienko - , TUD Dresden University of Technology (Author)
  • A. K. Bera - , Bhabha Atomic Research Center (BARC) (Author)
  • G. Aslan Cansever - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • S. Kamusella - , TUD Dresden University of Technology (Author)
  • A. Maljuk - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • C. G. F. Blum - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • L. T. Corredor - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • A. U. B. Wolter - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • S. M. Yusuf - , Bhabha Atomic Research Center (BARC) (Author)
  • M. Frontzek - , Oak Ridge National Laboratory (Author)
  • L. Keller - , Paul Scherrer Institute (Author)
  • M. Iakovleva - , Leibniz Institute for Solid State and Materials Research Dresden, Russian Academy of Sciences, RAS - Zavoisky Physical-Technical Institute, Kazan Scientific Center (Author)
  • E. Vavilova - , RAS - Zavoisky Physical-Technical Institute, Kazan Scientific Center (Author)
  • H. -J. Grafe - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • V. Kataev - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • H. -H. Klauss - , TUD Dresden University of Technology (Author)
  • D. S. Inosov - , TUD Dresden University of Technology (Author)
  • S. Wurmehl - , TUD Dresden University of Technology (Author)
  • B. B. Buechner - , TUD Dresden University of Technology (Author)

Abstract

We report the structural, magnetic, and thermodynamic properties of the double perovskite compound La2CuIrO6 from x-ray, neutron diffraction, neutron depolarization, dc magnetization, ac susceptibility, specific heat, muon-spin-relaxation (mu SR), electron-spin-resonance (ESR) and nuclear magnetic resonance (NMR) measurements. Below similar to 113 K, short-range spin-spin correlations occur within the Cu2+ sublattice. With decreasing temperature, the Ir4+ sublattice is progressively involved in the correlation process. Below T = 74 K, the magnetic sublattices of Cu (spin s = 1/2) and Ir (pseudospin j = 1/2) in La2CuIrO6 are strongly coupled and exhibit an antiferromagnetic phase transition into a noncollinear magnetic structure accompanied by a small uncompensated transverse moment. A weak anomaly in ac susceptibility as well as in the NMR and mu SR spin lattice relaxation rates at 54 K is interpreted as a cooperative ordering of the transverse moments which is influenced by the strong spin-orbit coupled 5d ion Ir4+. We argue that the rich magnetic behavior observed in La2CuIrO6 is related to complex magnetic interactions between the strongly correlated spin-only 3d ions with the strongly spin-orbit coupled 5d transition ions where a combination of the spin-orbit coupling and the low symmetry of the crystal lattice plays a special role for the spin structure in the magnetically ordered state.

Details

Original languageEnglish
Article number144437
Number of pages16
JournalPhysical Review B
Volume94
Issue number14
Publication statusPublished - 25 Oct 2016
Peer-reviewedYes
Externally publishedYes

External IDs

Scopus 84994201531

Keywords

Keywords

  • MAGNETIC-PROPERTIES, TRANSITION, CRYSTAL, IRIDIUM, HEAT

Library keywords