New insights into solvent-induced structural changes of 13C labelled metal-organic frameworks by solid state NMR

Marcus Rauche; Sebastian Ehrling; Simon Krause; Irena Senkovska; Stefan Kaskel; Eike Brunner

doi:10.1039/c9cc04298a

New insights into solvent-induced structural changes of ¹³C labelled metal-organic frameworks by solid state NMR

Research output: Contribution to journal › Research article › Contributed › peer-review

Contributors

Marcus Rauche - , Chair of Bioanalytical Chemistry (Author)
Sebastian Ehrling - , Chair of Inorganic Chemistry I (Author)
Simon Krause - , Chair of Inorganic Chemistry I, University of Groningen (Author)
Irena Senkovska - , Chair of Inorganic Chemistry I (Author)
Stefan Kaskel - , Chair of Inorganic Chemistry I (Author)
Eike Brunner - , Chair of Bioanalytical Chemistry (Author)

Abstract

Selective ¹³C-labelling of carboxylate carbons in the linker molecules of flexible metal-organic frameworks (MOFs) makes solid-state NMR spectroscopy very powerful to investigate solvent-induced local structural changes as demonstrated by ¹³C and ¹H NMR spectroscopy on the pillared layer MOF DUT-8(Ni). Selective identification of polar solvent-node interactions becomes feasible.

Details

Original language	English
Pages (from-to)	9140-9143
Number of pages	4
Journal	Chemical communications
Volume	55
Issue number	62
Publication status	Published - 2019
Peer-reviewed	Yes

External IDs

PubMed	31304489

Keywords

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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