Multiferroicity in rare-earth nickelates RNiO3

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • Gianluca Giovannetti - , Leiden University, University of Twente, National Research Council of Italy (CNR) (Author)
  • Sanjeev Kumar - , Leiden University, University of Twente (Author)
  • Daniel Khomskii - , University of Cologne (Author)
  • Silvia Picozzi - , National Research Council of Italy (CNR) (Author)
  • Jeroen Van Den Brink - , Leiden University, Radboud University Nijmegen, Stanford Linear Accelerator Center (SLAC), Leibniz Institute for Solid State and Materials Research Dresden (Author)

Abstract

We show that charge ordered rare-earth nickelates of the type RNiO 3 (R=Ho, Lu, Pr and Nd) are multiferroic with very large magnetically-induced ferroelectric (FE) polarizations. This we determine from first principles electronic structure calculations. The emerging FE polarization is directly tied to the long-standing puzzle of which kind of magnetic ordering is present in this class of materials: its direction and size indicate the type of ground-state spin configuration that is realized. Vice versa, the small energy differences between the different magnetic orderings suggest that a chosen magnetic ordering can be stabilized by cooling the system in the presence of an electric field.

Details

Original languageEnglish
Article number156401
JournalPhysical review letters
Volume103
Issue number15
Publication statusPublished - 7 Oct 2009
Peer-reviewedYes
Externally publishedYes

Keywords

ASJC Scopus subject areas