Modeling of hybrid relaxor-ferroelectric Ba(Zr0.2Ti0.8)O3 ceramics

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • I. A. Starkov - , St. Petersburg State Electrotechnical University, St. Petersburg National Research University of Information Technologies, Mechanics and Optics (ITMO) (Author)
  • G. Suchaneck - , Chair of Solid State Electronics (Author)
  • A. S. Starkov - , St. Petersburg National Research University of Information Technologies, Mechanics and Optics (ITMO) (Author)
  • G. Gerlach - , Chair of Solid State Electronics (Author)

Abstract

In this work, a model based on the existence of polarized nanoregions (PNRs) in a dielectric matrix is presented for a quantitative analysis of the hysteresis behavior in relaxor ferroelectrics. The PNRs are simulated by spheroids covered with a thin dielectric envelope. The electric field dependence of the polarization is described by the Landau-Ginzburg-Devonshire equation. The phase transition temperature of the individual spheroids appears to be strongly dependent on its orientation relatively to the external electric field. In addition, it depends on the aspect ratio of the spheroid and its size. The polarization in a relaxor ferroelectric was calculated by summation of the polarizations of individual spheroids. The final result is obtained by replacing the sum by a convolution integral of averaged angular dependence of polarization and the PNR size distribution. The obtained theoretical calculations are compared with experimental results.

Details

Original languageEnglish
Pages (from-to)8-15
Number of pages8
JournalFerroelectrics
Volume556
Issue number1
Publication statusPublished - 17 Feb 2020
Peer-reviewedYes

External IDs

ORCID /0000-0002-7062-9598/work/174430602

Keywords

Keywords

  • polar nanoregions, P–E hysteresis, Relaxor ferroelectrics