Mild Hydrosulfenylation of Olefins under Neutral Conditions Using a Defined NHC-Ligated Iron-Sulfur Catalyst
Research output: Contribution to journal › Research article › Contributed › peer-review
Contributors
Abstract
A defined NHC-Fe-S complex proved to be an efficient catalyst for the selective hydrosulfenylation of α,β-unsaturated ketones or vinylnitriles. A wide range of different aliphatic thiols were transferred in this atom-economic reaction into the corresponding thioethers. Mild reaction conditions, equimolar amounts of substrates, low catalyst loadings, and mild reaction conditions are characteristic for this transformation.
Details
Original language | English |
---|---|
Pages (from-to) | 3002-3005 |
Journal | ACS catalysis |
Volume | 3 |
Issue number | 12 |
Publication status | Published - Dec 2013 |
Peer-reviewed | Yes |
External IDs
Scopus | 84890391015 |
---|---|
ORCID | /0000-0001-8423-6173/work/142250791 |
Keywords
Keywords
- iron, sulfur, catalysis, addition, carbene ligand