Micro- and mesoporous carbide-derived carbon-selenium cathodes for high-performance lithium selenium batteries

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • Jung Tae Lee - , Georgia Institute of Technology (Author)
  • Hyea Kim - , Georgia Institute of Technology, Sila Nanotechnologies, Inc. (Author)
  • Martin Oschatz - , Chair of Inorganic Chemistry I (Author)
  • Dong Chan Lee - , Georgia Institute of Technology (Author)
  • Feixiang Wu - , Georgia Institute of Technology (Author)
  • Huan Ting Lin - , Georgia Institute of Technology (Author)
  • Bogdan Zdyrko - , Sila Nanotechnologies, Inc. (Author)
  • Won Il Cho - , Korea Institute of Science and Technology (Author)
  • Stefan Kaskel - , Chair of Inorganic Chemistry I (Author)
  • Gleb Yushin - , Georgia Institute of Technology (Author)

Abstract

Nanocomposites of selenium (Se) and ordered mesoporous silicon carbide-derived carbon (OM-SiC-CDC) are prepared for the first time and studied as cathodes for lithium-selenium (Li-Se) batteries. The higher concentration of Li salt in the electrolytes greatly improves Se utilization and cell cycle stability. Se-CDC shows significantly better performance characteristics than Se-activated carbon nanocomposites with similar physical properties. Se-CDC also exhibits better rate performance and cycle stability compared to similarly produced sulfur (S)-CDC for Li/S batteries.

Details

Original languageEnglish
Article number1400981
JournalAdvanced energy materials
Volume5
Issue number1
Publication statusPublished - 1 Jan 2015
Peer-reviewedYes