Magnetism and site exchange in CuFeAs and CuFeSb: A microscopic and theoretical investigation

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • Sirko Kamusella - , Technische Universität Dresden (Author)
  • Hans-Henning Klauss - , Technische Universität Dresden (Author)
  • Gohil S. Thakur - , Indian Institute of Technology Hyderabad, Indian Institute of Technology Delhi (IITD) (Author)
  • Zeba Haque - , Indian Institute of Technology Delhi (IITD) (Author)
  • Laxmi C. Gupta - , Indian Institute of Technology Delhi (IITD) (Author)
  • Ashok K. Ganguli - , Chennai Mathematical Institute (Author)
  • Inga Kraft - , Max Planck Institute for Gravitational Physics (Albert Einstein Institute) (Author)
  • Ulrich Burkhardt - , Max Planck Institute for Gravitational Physics (Albert Einstein Institute) (Author)
  • Helge Rosner - , Max Planck Institute for Gravitational Physics (Albert Einstein Institute) (Author)
  • Hubertus Luetkens - , Paul Scherrer Institute (Author)
  • Jeffrey W. Lynn - , National Institute of Standards and Technology (NIST) (Author)
  • Yang Zhao - , University of Maryland, College Park (Author)

Abstract

We have investigated the magnetic ground state of CuFeAs and CuFeSb by means of Fe-57-Mossbauer spectroscopy, muon spin rotation/ relaxation (mu SR), neutron diffraction, and electronic structure calculations. Both materials share the 111-LiFeAs crystal structure and are closely related to the class of iron-based superconductors. In both materials there is a considerable occupancy of the Cu site by Fe, which leads to ferromagnetic moments, which are magnetically strongly coupled to the regular Fe site magnetism. Our study shows that CuFeAs is close to an antiferromagnetic instability, whereas a ferromagnetic ground state is observed in CuFeSb, supporting theoretical models of anion height driven magnetism.

Details

Original languageEnglish
Article number094415
Number of pages13
JournalPhysical Review B
Volume95
Issue number9
Publication statusPublished - 13 Mar 2017
Peer-reviewedYes

External IDs

Scopus 85015907665

Keywords

Keywords

  • IRON, SUPERCONDUCTOR, MOSSBAUER, LIFEAS

Library keywords