Magnetic properties of the spin-1 chain compound NiCl3C6H5CH2CH2NH3

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • F. Lipps - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • A. H. Arkenbout - , University of Groningen (Author)
  • A. Polyakov - , University of Groningen (Author)
  • M. Günther - , Chair of Solid State Physics/Electronic Properties (Author)
  • T. Salikhov - , RAS - Zavoisky Physical-Technical Institute, Kazan Scientific Center (Author)
  • E. Vavilova - , RAS - Zavoisky Physical-Technical Institute, Kazan Scientific Center (Author)
  • H. H. Klauss - , Chair of Solid State Physics/Electronic Properties (Author)
  • B. Büchner - , Chair of Experimental Solid State Physics, Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • T. M. Palstra - , University of Groningen (Author)
  • V. Kataev - , Leibniz Institute for Solid State and Materials Research Dresden (Author)

Abstract

We report experimental results of the static magnetization, ESR and NMR spectroscopic measurements of the Ni-hybrid compound NiCl3C6H5CH2CH2NH3. In this material NiCl3 octahedra are structurally arranged in chains along the crystallographic a axis. According to the static susceptibility and ESR data Ni2+ spins S = 1 are isotropicand are coupled antiferromagnetically (AFM) along the chain with the exchange constant J = 25.5 K. These are im-portant prerequisites for the realization of the so-called Haldane spin-1 chain with the spin-singlet ground state and a quantum spin gap. However, experimental results evidence AFM order at TN ≈ 10 K presumably due to small interchain couplings. Interestingly, frequency-, magnetic field-, and temperature-dependent ESR measurements, as well as the NMR data, reveal signatures which could presumably indicate an inhomogeneous ground state of co-existent mesoscopically spatially separated AFM ordered and spin-singlet state regions similar to the situation ob-served before in some spin-diluted Haldane magnets.

Details

Original languageEnglish
Pages (from-to)1626-1633
Number of pages8
Journal Fizika nizkich temperatur : ežemesjačnyj naučnyj žurnal
Volume43
Issue number11
Publication statusPublished - Nov 2017
Peer-reviewedYes

Keywords

ASJC Scopus subject areas

Keywords

  • ESR, NMR, Spin chains