Magnetic properties of the spin-1 chain compound NiCl3C6H5CH2CH2NH3
Research output: Contribution to journal › Research article › Contributed › peer-review
Contributors
Abstract
We report experimental results of the static magnetization, ESR and NMR spectroscopic measurements of the Ni-hybrid compound NiCl3C6H5CH2CH2NH3. In this material NiCl3 octahedra are structurally arranged in chains along the crystallographic a axis. According to the static susceptibility and ESR data Ni2+ spins S = 1 are isotropicand are coupled antiferromagnetically (AFM) along the chain with the exchange constant J = 25.5 K. These are im-portant prerequisites for the realization of the so-called Haldane spin-1 chain with the spin-singlet ground state and a quantum spin gap. However, experimental results evidence AFM order at TN ≈ 10 K presumably due to small interchain couplings. Interestingly, frequency-, magnetic field-, and temperature-dependent ESR measurements, as well as the NMR data, reveal signatures which could presumably indicate an inhomogeneous ground state of co-existent mesoscopically spatially separated AFM ordered and spin-singlet state regions similar to the situation ob-served before in some spin-diluted Haldane magnets.
Details
Original language | English |
---|---|
Pages (from-to) | 1626-1633 |
Number of pages | 8 |
Journal | Fizika nizkich temperatur : ežemesjačnyj naučnyj žurnal |
Volume | 43 |
Issue number | 11 |
Publication status | Published - Nov 2017 |
Peer-reviewed | Yes |
Keywords
ASJC Scopus subject areas
Keywords
- ESR, NMR, Spin chains