Magnetic properties of DyFe5−xCoxAl7: Suppression of exchange interactions and magnetocrystalline anisotropy by Co substitution
Research output: Contribution to journal › Research article › Contributed › peer-review
Contributors
Abstract
In 3d−4f intermetallic compounds, a Co substitution for Fe usually strengthens the exchange interactions due to a shift of the Fermi energy to a region of the 3d band with higher density of states. Here, we study the influence of Co on the magnetism of ferrimagnetic DyFe5Al7 using magnetization measurements in static (up to 14 T) and pulsed (up to 58 T) magnetic fields. We find that the homogeneity range of DyFe5−xCoxAl7 is limited to x≤2.5. The Co substitution for Fe produces a strong detrimental effect on the 3d−3d intrasublattice exchange interactions, which leads to a pronounced decrease of the Curie temperature and of the 3d−4f intersublattice exchange field. A reduction of the density of states at the Fermi level might occur due to a broadening of the 3d band. A decrease of the rare-earth contribution to the magnetic anisotropy energy is also observed with increasing Co content. This is attributed to a competition between the Fe and Co contributions to the crystal electric field at the Dy site.
Details
Original language | English |
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Pages (from-to) | 715-722 |
Number of pages | 8 |
Journal | Journal of alloys and compounds |
Volume | 741 |
Publication status | Published - 15 Apr 2018 |
Peer-reviewed | Yes |
Keywords
ASJC Scopus subject areas
Keywords
- Exchange interactions, Ferrimagnetism, Field-induced transition, Magnetic anisotropy