Magnetic phase diagram and spin Hamiltonian of antiferromagnet Cs2CoI4

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Contributors

  • S. D. Nabi - , ETH Zurich (Author)
  • L. Facheris - , ETH Zurich (Author)
  • V. Romerio - , ETH Zurich (Author)
  • V. Kocsis - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • K. Yu Povarov - , Helmholtz-Zentrum Dresden-Rossendorf (HZDR), Würzburg-Dresden Cluster of Excellence ctd.qmat (Author)
  • D. Sheptyakov - , Paul Scherrer Institute (PSI) (Author)
  • J. Lass - , Paul Scherrer Institute (PSI) (Author)
  • D. G. Mazzone - , Paul Scherrer Institute (PSI) (Author)
  • H. Kikuchi - , The University of Tokyo (Author)
  • T. Masuda - , The University of Tokyo (Author)
  • S. A. Barnett - , Diamond Light Source (Author)
  • D. R. Allan - , Diamond Light Source (Author)
  • Z. Yan - , ETH Zurich (Author)
  • S. Gvasaliya - , ETH Zurich (Author)
  • A. Zheludev - , ETH Zurich (Author)

Abstract

We report comprehensive thermodynamic and neutron scattering measurements on the S=3/2 antiferromagnet Cs2CoI4, a member of the thoroughly studied family of frustrated magnets Cs2MX4 (M=Cu, Co, Ru, X=Br, Cl, I, O). Unlike previously studied members, Cs2CoI4 undergoes a structural phase transition, for which we determine the low-temperature crystallographic structure. The resulting symmetry reduction strongly affects both the magnetic exchange interactions and single-ion anisotropy. Despite the large parameter space, we propose a minimal magnetic Hamiltonian that reasonably captures the observed excitation spectrum, analyzed using extended SU(4) linear spin-wave theory.

Details

Original languageEnglish
Article number054420
JournalPhysical review materials
Volume10
Issue number5
Publication statusPublished - 1 May 2026
Peer-reviewedYes