Lander on Cu(2 1 1) - Selective adsorption and surface restructuring by a molecular wire

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • Leo Gross - , Free University of Berlin (Author)
  • Francesca Moresco - , Free University of Berlin (Author)
  • Micol Alemani - , Free University of Berlin (Author)
  • Hao Tang - , Center for Materials Elaboration and Structural Studies (Author)
  • André Gourdon - , Center for Materials Elaboration and Structural Studies (Author)
  • Christian Joachim - , Center for Materials Elaboration and Structural Studies (Author)
  • Karl Heinz Rieder - , Free University of Berlin (Author)

Abstract

The large organic molecule C90H98, called Lander, has been investigated on the Cu(2 1 1) surface by low temperature scanning tunnelling microscopy (LT-STM). Different adsorption geometries, which differ in the internal conformation and the orientation of the molecule, are described. These adsorption conformations have been determined by elastic scattering quantum chemistry calculations (ESQC). For T > 120 K, adsorption at selected step edges is combined with an adsorbate induced restructuring. The reconstruction is revealed by lateral STM manipulation and could be imaged with atomic resolution. It has the form of a (3 1 1) facet. The restructured steps can be used as a guidance for lateral manipulation of large molecules.

Details

Original languageEnglish
Pages (from-to)750-756
Number of pages7
JournalChemical physics letters
Volume371
Issue number5-6
Publication statusPublished - 14 Apr 2003
Peer-reviewedYes
Externally publishedYes

External IDs

ORCID /0000-0001-9607-8715/work/142252641