Integration of zinc oxide nanoparticles into transparent poly(butanediolmonoacrylate) via photopolymerisation

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • H. Althues - , TUD Dresden University of Technology (Author)
  • P. Simon - , Max Planck Institute for Chemical Physics of Solids (Author)
  • F. Philipp - , TUD Dresden University of Technology (Author)
  • S. Kaskel - , Chair of Inorganic Chemistry I (Author)

Abstract

A new method for the preparation of transparent ZnO/PBDMA nanocomposites (PBDMA = poly(butanediolmonoacrylate)) is reported. Zinc oxide nanocrystals (4-10 nm) were synthesized in ethanol and then transferred into butanediolmonoacrylate (BDMA) to obtain a transparent and stable colloidal suspension. No further growth or aggregation of the particles could be observed, after dispersing the particles in the monomer. Effective size control in the range of 6-10 nm and concentrations up to 10 wt% zinc oxide were demonstrated for these systems. The particles and suspensions were characterized by transmission electron microscopy, X-ray diffraction, UV-VIS spectroscopy and dynamic light scattering. The addition of trimethylolpropane triacrylate (TMPTA) and a photoinitiator to the ZnO/BDMA suspension lead to a UV-curable liquid. Photoinduced polymerization was used to produce transparent nanocomposites containing the nanoparticles. The material exhibits a strong UV absorption below 360 nm, a high transmission (90%) in the visible spectral range and a green photoluminescence.

Details

Original languageEnglish
Pages (from-to)409-413
Number of pages5
JournalJournal of nanoscience and nanotechnology
Volume6
Issue number2
Publication statusPublished - Feb 2006
Peer-reviewedYes

External IDs

PubMed 16573039

Keywords

Keywords

  • Nanocomposite, PBDMA, Photopolymerization, Transparent, Zinc Oxide

Library keywords