Integration of zinc oxide nanoparticles into transparent poly(butanediolmonoacrylate) via photopolymerisation
Research output: Contribution to journal › Research article › Contributed › peer-review
Contributors
Abstract
A new method for the preparation of transparent ZnO/PBDMA nanocomposites (PBDMA = poly(butanediolmonoacrylate)) is reported. Zinc oxide nanocrystals (4-10 nm) were synthesized in ethanol and then transferred into butanediolmonoacrylate (BDMA) to obtain a transparent and stable colloidal suspension. No further growth or aggregation of the particles could be observed, after dispersing the particles in the monomer. Effective size control in the range of 6-10 nm and concentrations up to 10 wt% zinc oxide were demonstrated for these systems. The particles and suspensions were characterized by transmission electron microscopy, X-ray diffraction, UV-VIS spectroscopy and dynamic light scattering. The addition of trimethylolpropane triacrylate (TMPTA) and a photoinitiator to the ZnO/BDMA suspension lead to a UV-curable liquid. Photoinduced polymerization was used to produce transparent nanocomposites containing the nanoparticles. The material exhibits a strong UV absorption below 360 nm, a high transmission (90%) in the visible spectral range and a green photoluminescence.
Details
Original language | English |
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Pages (from-to) | 409-413 |
Number of pages | 5 |
Journal | Journal of nanoscience and nanotechnology |
Volume | 6 |
Issue number | 2 |
Publication status | Published - Feb 2006 |
Peer-reviewed | Yes |
External IDs
PubMed | 16573039 |
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Keywords
ASJC Scopus subject areas
Keywords
- Nanocomposite, PBDMA, Photopolymerization, Transparent, Zinc Oxide