Integration of an N-Heterocyclic Carbene Precursor into a Covalent Triazine Framework for Organocatalysis

Erik Troschke; Khoa Dang Nguyen; Silvia Paasch; Johannes Schmidt; Georg Nickerl; Irena Senkovska; Eike Brunner; Stefan Kaskel

doi:10.1002/chem.201804373

Integration of an N-Heterocyclic Carbene Precursor into a Covalent Triazine Framework for Organocatalysis

Research output: Contribution to journal › Research article › Contributed › peer-review

Contributors

Erik Troschke - , Chair of Inorganic Chemistry I (Author)
Khoa Dang Nguyen - , TUD Dresden University of Technology (Author)
Silvia Paasch - , Chair of Bioanalytical Chemistry (Author)
Johannes Schmidt - , Technical University of Berlin (Author)
Georg Nickerl - , Chair of Inorganic Chemistry I (Author)
Irena Senkovska - , Chair of Inorganic Chemistry I (Author)
Eike Brunner - , Chair of Bioanalytical Chemistry (Author)
Stefan Kaskel - , Chair of Inorganic Chemistry I (Author)

Abstract

The successful incorporation of a thermally fragile imidazolium moiety into a covalent triazine framework resulted in a heterogeneous organocatalyst active in carbene-catalyzed umpolung reaction. The structural integrity of the imidazolium moiety was confirmed by combining solid-state NMR and XPS experiments.

Details

Original language	English
Pages (from-to)	18629-18633
Number of pages	5
Journal	Chemistry - A European Journal
Volume	24
Issue number	70
Publication status	Published - 4 Oct 2018
Peer-reviewed	Yes

External IDs

PubMed	30284341

Keywords

ASJC Scopus subject areas

Catalysis
Organic Chemistry

Keywords

covalent triazine frameworks, microporous materials, N-heterocyclic carbenes, organocatalysis, porous polymers

Library keywords

540 Chemistry and allied sciences

Research Portal of the TU Dresden

Contributors

Abstract

Details

External IDs

Keywords

ASJC Scopus subject areas

Keywords

Library keywords