Infrared investigations of the one-dimensional organic conductors (perylene) 2 M (mnt) 2, M = Au, Pt

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • N. Drichko - , University of Stuttgart (Author)
  • S. Kaiser - , University of Stuttgart (Author)
  • R. Shewmon - , University of Stuttgart (Author)
  • J. Eckstein - , University of Stuttgart (Author)
  • M. Dressel - , University of Stuttgart (Author)
  • M. Matos - , Instituto de Telecomunicações (Author)
  • R. T. Henriques - , Instituto de Telecomunicações (Author)
  • M. Almeida - , Instituto Tecnológico e Nuclear (Author)

Abstract

The optical properties of the one-dimensional organic conductor (perylene) 2Pt(mnt) 2 and its Au analogue have been investigated at ambient and low temperatures. The spectra along the stacks of the molecules show a simple Drude behavior with no detectable influence of electron-electron interactions. Basing on the spectra for different polarizations an assignment of the vibrational modes is made. Perpendicular to the stacks, a wide band observed in the mid-infrared range evidences a charge transfer between perylene and anion stacks. The electronic properties are discussed in comparison with other quasi-one-dimensional synthetic metals.

Details

Original languageEnglish
Pages (from-to)283-289
Number of pages7
JournalEuropean Physical Journal B
Volume78
Issue number3
Publication statusPublished - Dec 2010
Peer-reviewedYes
Externally publishedYes

External IDs

ORCID /0000-0001-9862-2788/work/142255394