Incommensurately modulated CeSi1.82
Research output: Contribution to journal › Research article › Contributed › peer-review
Contributors
Abstract
An incommensurately modulated structure of CeSi1.82 as determined by single-crystal X-ray diffraction at room temperature is reported. The observed satellite reflections reduce the orthorhombic symmetry of the X-ray pattern to a monoclinic one. This suggests the description of the modulated structure in the monoclinic superspace group I2/b(aβ0)00. The modulation wave vector was determined to q→ = 0.410(1) · a →* + 0.610(1) · b→*. The refinement was done using harmonic modulation functions for the displacement and the occupation probability of the atoms, the quality parameters converged to Robs = 3.33% (Robs = 2.56% for the main reflections, Robs = 8.88% for the 1st order satellite reflections and R obs = 33.06% for the 2nd order satellite reflections). The origin of the observed satellite reflections is attributed to a modulation of the partly occupied Si site caused by composition changes within the crystal.
Details
| Original language | English |
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| Pages (from-to) | 128-134 |
| Number of pages | 7 |
| Journal | Zeitschrift fur Kristallographie |
| Volume | 220 |
| Issue number | 2-3 |
| Publication status | Published - 2005 |
| Peer-reviewed | Yes |
External IDs
| ORCID | /0000-0001-7523-9313/work/159171516 |
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Keywords
Sustainable Development Goals
ASJC Scopus subject areas
Keywords
- Cerium suicide, Modulated structure, Non-stoichiometry, Satellite reflections, Single crystal structure analysis, Superspace group, X-ray diffraction