In situ synthesis of an imidazolate-4-amide-5-imidate ligand and formation of a microporous zinc-organic framework with H2-and CO 2-Storage Ability
Research output: Contribution to journal › Research article › Contributed › peer-review
Contributors
Abstract
"(Figure Presented)" Narrow channels with polar walls are the structural and functional features responsible for the high capacity of a zinc-organic framework based on an imidazolate-amide-imidate ligand for the uptake of H2 and CO2 (see structure: orange Zn, blue N, red O, dark gray C, light gray H). The rigid and stable chelating ligand was synthesized in situ by partial hydrolysis of a dicyanoimidazole compound.
Details
Original language | English |
---|---|
Pages (from-to) | 1258-1262 |
Number of pages | 5 |
Journal | Angewandte Chemie - International Edition |
Volume | 49 |
Issue number | 7 |
Publication status | Published - 8 Feb 2010 |
Peer-reviewed | Yes |
External IDs
PubMed | 20084655 |
---|
Keywords
ASJC Scopus subject areas
Keywords
- Gas sorption, Metal-organic frameworks, Microporous materials, N,O ligands, Solvothermal synthesis