In situ study of the thermoresponsive behavior of micropatterned hydrogel films by imaging ellipsometry
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Contributors
Abstract
A patterned hydrogel was immobilized on a polymer substrate by low-pressure argon plasma treatment using a masking technique. The polymer sample showed a thermoresponsive aggregation behavior in the region of 35-37 degrees C. The micropatterned, thermoresponsive hydrogel film has been characterized with imaging ellipsometry. The characterization was carried out on the dry film as well as on a swollen sample in water. The thermoresponsive behavior was studied in deionized water by temperature-dependent measurements in a solid-liquid cell. Through imaging ellipsometry, it was possible to distinguish the different regions of interest on a micrometer scale and to follow the swelling of the hydrogel part as a function of the temperature. It was possible to visualize the swelling as 3D profiles of Delta at various temperatures. Long-term changes of the sample could also be detected, which cannot be picked up by conventional ellipsometry.
Details
Original language | English |
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Pages (from-to) | 2317-22 |
Number of pages | 6 |
Journal | Langmuir |
Volume | 21 |
Issue number | 6 |
Publication status | Published - 15 Mar 2005 |
Peer-reviewed | Yes |
Externally published | Yes |
External IDs
Scopus | 15844396842 |
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ORCID | /0000-0003-0189-3448/work/173985723 |