Immobilization of a molecular cobaloxime catalyst for hydrogen evolution on a mesoporous metal oxide electrode

Research output: Contribution to journal › Research article › Contributed › peer-review

Contributors

  • Nicoleta M. Muresan - , University of Cambridge (Author)
  • Janina Willkomm - , University of Cambridge (Author)
  • Dirk Mersch - , University of Cambridge (Author)
  • Yana Vaynzof - , University of Cambridge (Author)
  • Erwin Reisner - , University of Cambridge (Author)

Abstract

Energizing Cobalt on a 3D Electrode: An optically transparent mesoporous ITO film was derivatized with the novel proton reducing cobalt catalyst [Co]. The hybrid electrode showed high current densities, and spectroelectrochemical studies and extensive surface characterization demonstrate that the immobilized molecular catalyst remained intact on the electrode when applying a low potential.

Details

Original languageEnglish
Pages (from-to)12749-12753
Number of pages5
JournalAngewandte Chemie - International Edition
Volume51
Issue number51
Publication statusPublished - 14 Dec 2012
Peer-reviewedYes
Externally publishedYes

Keywords

Sustainable Development Goals

ASJC Scopus subject areas

Keywords

  • cobalt, heterogeneous catalysis, hybrid materials, proton reduction, water splitting

Library keywords