Hyperbranched polymers - All problems solved after 15 years of research?

Research output: Contribution to journalReview articleContributedpeer-review

Contributors

Abstract

Fifteen years of research on hyperbranched polymers in the group of Brigitte Voit are described, with a focus first on hyperbranched polyester synthesis and then on the addition and cycloaddition reactions used for the preparation of the hyperbranched structure. The characterization of structural details and bulk, solution, and thin-film properties is highlighted, and steps toward the elucidation of a general property profile of hyper-branched polymers are discussed. Some effects of hyperbranched polymers in reactive formulations and blends and in thin films are addressed that can lead to applications in coatings, as additives, and in microelectronics or sensorics. The great progress possible in the last years is shown, but open questions and unsolved problems are also pointed out. (c) 2005 Wiley Periodicals.

Details

Original languageGerman
Pages (from-to)2679-2699
Number of pages21
JournalJournal of Polymer Science, Part A: Polymer Chemistry
Volume43
Issue number13
Publication statusPublished - 1 Jul 2005
Peer-reviewedYes

External IDs

Scopus 24344435969
ORCID /0000-0002-4531-691X/work/148607707

Keywords

Keywords

  • Condensing vinyl polymerization, Molecular-weight distribution, Ring-opening polymerization, Transfer radical copolymerization, Highly branched polymers, Bb'(2) type monomers, One-step synthesis, Aromatic polyamide, Graft-copolymers, Chain-end