High pressure intramolecular Diels-Alder reactions of vinylsulfonates and vinylsulfonamides
Research output: Contribution to journal › Research article › Contributed › peer-review
Contributors
Abstract
Acceleration of the intramolecular Diels-Alder reaction of vinylsulfonic esters and amides bearing acyclic and carbocyclic 1,3-diene moieties by application of high pressure leads to excellent yields of sultones and sultams, respectively, at ambient temperature. The influence of pressure on the stereoselectivity of these processes has been investigated. (C) 2000 Elsevier Science Ltd.
Details
| Original language | English |
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| Pages (from-to) | 873-879 |
| Number of pages | 7 |
| Journal | Tetrahedron |
| Volume | 56 |
| Issue number | 6 |
| Publication status | Published - 4 Feb 2000 |
| Peer-reviewed | Yes |
External IDs
| ORCID | /0000-0001-8423-6173/work/171062641 |
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Keywords
ASJC Scopus subject areas
Keywords
- Diels-Alder reactions, Pressure, Reactions under, Sultams, Sultones