Hidden Photoexcitations Probed by Multipulse Photoluminescence

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • Alexandr Marunchenko - , Lund University (Author)
  • Jitendra Kumar - , Lund University (Author)
  • Dmitry Tatarinov - , St. Petersburg National Research University of Information Technologies, Mechanics and Optics (ITMO) (Author)
  • Anatoly P. Pushkarev - , St. Petersburg National Research University of Information Technologies, Mechanics and Optics (ITMO) (Author)
  • Yana Vaynzof - , Center for Advancing Electronics Dresden (cfaed), Chair of Emerging Electronic Technologies (gB/IFW and cfaed), Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • Ivan G. Scheblykin - , Lund University (Author)

Abstract

Time-resolved photoluminescence is a validated method for tracking the photoexcited carrier dynamics in luminescent materials. This technique probes the photoluminescence decays upon a periodic excitation by short laser pulses. Herein, we show that this approach cannot directly detect hidden photoexcitations with much slower dynamics than the photoluminescence decay. We demonstrate a new method based on a multipulse excitation scheme that enables an unambiguous detection and an easily interpreted tracking of these hidden species. The multipulse excitation consists of a single pulse (Read) followed by a burst of many closely separated pulses (Write) and finally another single pulse (Read). To illustrate the efficacy of the Read-Write-Read excitation scheme, we apply it to metal halide perovskites to directly visualize carrier trapping, extract the concentration of trapped charges, and determine the rate constant of trap depopulation. The developed approach allows studying performance-limiting processes in energy devices using a versatile, highly applicable all-optical method.

Details

Original languageEnglish
Pages (from-to)5898-5906
Number of pages9
JournalACS energy letters
Volume9
Issue number12
Publication statusPublished - 13 Dec 2024
Peer-reviewedYes