Guanosine-based hydrogen-bonded 2D scaffolds: metal-free formation of G-quartet and G-ribbon architectures at the solid/liquid interface
Research output: Contribution to journal › Research article › Contributed › peer-review
Contributors
Abstract
We report on the synthesis and self-assembly of three novel lipophilic guanosine derivatives exposing a ferrocene moiety in the C(5') position of the sugar unit. Their self-association in solution, and at the solid/liquid interface, can be tuned by varying the size and nature of the C(8)-substituent, leading to the generation of either G-ribbons, lamellar G-dimer based arrays or the G4 cation-free architectures.
Details
Original language | English |
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Pages (from-to) | 11677-80 |
Number of pages | 4 |
Journal | Chemical Communications |
Volume | 51 |
Issue number | 58 |
Publication status | Published - 25 Jul 2015 |
Peer-reviewed | Yes |
External IDs
PubMed | 26102583 |
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Scopus | 84936097793 |
ORCID | /0000-0001-8121-8041/work/142240887 |
Keywords
Keywords
- Ferrous Compounds/chemistry, Guanosine/chemistry, Hydrogen Bonding, Metallocenes