Glassy Dynamics and Glass Transition in Thin Polymer Layers of PMMA Deposited on Different Substrates

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • Michael Erber - , Leibniz Institute of Polymer Research Dresden (Author)
  • Martin Tress - , University Hospital Leipzig (Author)
  • Emmanuel U. Mapesa - , University Hospital Leipzig (Author)
  • Anatoli Serghei - , University of Massachusetts Amherst (Author)
  • Klaus-Jochen Eichhorn - , Leibniz Institute of Polymer Research Dresden (Author)
  • Brigitte Voit - , Leibniz Institute of Polymer Research Dresden (Author)
  • Friedrich Kremer - , University Hospital Leipzig (Author)

Abstract

Spectroscopic vis-ellipsometry and broadband dielectric spectroscopy (BDS) are combined to study the glassy dynamics of thin (>= 10 nm) layers of atactic poly(methyl methacrylate) (PM MA) annealed and measured under identical conditions. In order to unravel a possible effect of the underlying substrate, the interfacial interactions are systematically modified ranging from strong attractive interactions for covalently bonded PM MA brushes with high grafting density and for native silicon oxide (Si/SiOx) to weak and strong repulsive interactions as realized by Au-coated and HMDS-treated Si/SiOx surfaces, respectively. Down to the thinnest analyzed PM MA layers and independently from the applied substrate, both methods deliver-within the experimental accuracy (+/- 1 K for BDS and +/- 2 K for ellipsometry)-a coinciding result. The glassy dynamics arc not altered due to the one-dimensional confinement in these thin polymer layers. The results are discussed with respect to the highly controversial literature and the impact of the preparative conditions.

Details

Original languageEnglish
Pages (from-to)7729-7733
Number of pages5
JournalMacromolecules
Volume43
Issue number18
Publication statusPublished - 28 Sept 2010
Peer-reviewedYes
Externally publishedYes

External IDs

Scopus 78651336807
ORCID /0000-0002-4531-691X/work/148607818

Keywords

Keywords

  • Poly(methyl methacrylate), Temperature, Films, Confinement, Mobility, Probe