Generalization of the Davydov Ansatz by squeezing
Research output: Contribution to journal › Research article › Contributed › peer-review
Contributors
Abstract
We propose an extension of the Davydov Ansatz employing displaced squeezed states in the oscillator Hilbert space. The Dirac-Frenkel variational principle is used to derive the modified equations for the variational parameters. First numerical studies of the dynamics of the spin-boson model with a single bosonic degree of freedom reveal an overall improvement of the results as compared to the standard Davydov Ansatz. (C) 2016 Elsevier B.V. All rights reserved.
Details
Original language | English |
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Pages (from-to) | 99-107 |
Number of pages | 9 |
Journal | Chemical Physics |
Volume | 481 |
Publication status | Published - 20 Dec 2016 |
Peer-reviewed | Yes |
External IDs
Scopus | 84969211360 |
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WOS | 000389589700014 |
Keywords
Keywords
- Spin-boson model, Davydov Ansatz, Variational principle, Squeezed states, DYNAMICS, STATES