Generalization of the Davydov Ansatz by squeezing

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

Abstract

We propose an extension of the Davydov Ansatz employing displaced squeezed states in the oscillator Hilbert space. The Dirac-Frenkel variational principle is used to derive the modified equations for the variational parameters. First numerical studies of the dynamics of the spin-boson model with a single bosonic degree of freedom reveal an overall improvement of the results as compared to the standard Davydov Ansatz. (C) 2016 Elsevier B.V. All rights reserved.

Details

Original languageEnglish
Pages (from-to)99-107
Number of pages9
JournalChemical Physics
Volume481
Publication statusPublished - 20 Dec 2016
Peer-reviewedYes

External IDs

Scopus 84969211360
WOS 000389589700014

Keywords

Keywords

  • Spin-boson model, Davydov Ansatz, Variational principle, Squeezed states, DYNAMICS, STATES