General Design Concepts for CAPodes as Ionologic Devices
Research output: Contribution to journal › Research article › Contributed › peer-review
Contributors
Abstract
Capacitive analogues of semiconductor diodes (CAPodes) present a new avenue for energy-efficient and nature-inspired next-generation computing devices. Here, we disclose the generalized concept for bias-direction-adjustable n- and p-CAPodes based on selective ion sieving. Controllable-unidirectional ion flux is realized by blocking electrolyte ions from entering sub-nanometer pores. The resulting CAPodes exhibit charge-storage characteristics with a high rectification ratio (96.29 %). The enhancement of capacitance is attributed to the high surface area and porosity of an omnisorbing carbon as counter electrode. Furthermore, we demonstrate the use of an integrated device in a logic gate circuit architecture to implement logic operations (‘OR’, ‘AND’). This work demonstrates CAPodes as a generalized concept to achieve p-n and n-p analogue junctions based on selective ion electrosorption, provides a comprehensive understanding and highlights applications of ion-based diodes in ionologic architectures.
Details
Original language | English |
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Article number | e202305397 |
Journal | Angewandte Chemie - International Edition |
Volume | 62 |
Issue number | 34 |
Publication status | Published - 21 Aug 2023 |
Peer-reviewed | Yes |
External IDs
WOS | 001027640900001 |
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Keywords
ASJC Scopus subject areas
Keywords
- Capacitive Analogues of Semiconductor Diodes, Ionologic Devices., Porous Carbon, Supercapacitors, Ionologic Devices