Frustration-driven unconventional magnetism in the Mn2+ (S = 5/2) based two-dimensional triangular-lattice antiferromagnet Ba3MnTa2O9

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • Romario Mondal - , Indian Institute of Technology, Dhanbad (Author)
  • Sk Soyeb Ali - , Bennett University (Author)
  • Saikat Nandi - , Indian Institute of Technology Bombay (IITB) (Author)
  • S. Chattopadhyay - , Government of India, Department of Atomic Energy (Author)
  • S. Gaß - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • L. T. Corredor - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • A. U.B. Wolter - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • V. Kataev - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • B. Büchner - , Clusters of Excellence ct.qmat: Complexity and Topology in Quantum Matter, Chair of Experimental Solid State Physics, Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • A. Alfonsov - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • S. Wurmehl - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • A. V. Mahajan - , Indian Institute of Technology Bombay (IITB) (Author)
  • S. K. Panda - , Bennett University (Author)
  • T. Dey - , Indian Institute of Technology, Dhanbad (Author)

Abstract

The triple perovskite oxide Ba3MnTa2O9 has been synthesized, and its magnetic properties have been investigated through dc and ac magnetization, specific heat, electron spin resonance measurements, and density functional theory (DFT) calculations. Mn2+ (S = 5/2) ions are the only magnetic species present in the material. These Mn2+ ions constitute a quasi-two-dimensional triangular network in the crystallographic ab plane. Magnetization and specific heat measurements reveal the absence of any long-range magnetic order down to 0.5 K despite the presence of antiferromagnetic correlations between the magnetic ions, suggesting the presence of geometric frustration in the material. The entropy release is lower than the expected theoretical value of R ln(6), further suggesting the presence of frustration. First-principles calculations using DFT and atomistic spin dynamics simulations further support this lack of static magnetic order even at low temperatures and identify the competing magnetic interactions along with the quasi-two-dimensional magnetic dimensionality as the underlying origin of this unconventional magnetic behavior.

Details

Original languageEnglish
Article number155153
JournalPhysical Review B
Volume112
Issue number15
Publication statusPublished - 23 Oct 2025
Peer-reviewedYes