Feasibility study on high-energy-density almost-solid-state sodium batteries with thin ceramic Na3.4Zr2Si2.4P0.6O12 separators

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • Ansgar Lowack - , Chair of Inorganic Non-Metallic Materials, Fraunhofer Institute for Ceramic Technologies and Systems (Author)
  • Rafael Anton - , Fraunhofer Institute for Ceramic Technologies and Systems (Author)
  • Dörte Wagner - , Fraunhofer Institute for Ceramic Technologies and Systems (Author)
  • Monika Bhardwaj - , Jülich Research Centre (Author)
  • Stephan Prünte - , Jülich Research Centre (Author)
  • Enkhtsetseg Dashjav - , Jülich Research Centre (Author)
  • Kristian Nikolowski - , Fraunhofer Institute for Ceramic Technologies and Systems (Author)
  • Frank Tietz - , Jülich Research Centre (Author)
  • Katja Wätzig - , Fraunhofer Institute for Ceramic Technologies and Systems (Author)
  • Mihails Kusnezoff - , Fraunhofer Institute for Ceramic Technologies and Systems (Author)
  • Mareike Partsch - , Fraunhofer Institute for Ceramic Technologies and Systems (Author)
  • Alexander Michaelis - , Chair of Inorganic Non-Metallic Materials, Fraunhofer Institute for Ceramic Technologies and Systems (Author)

Abstract

This study investigates the feasibility and limitations of almost-solid-state sodium batteries (Na-aSSBs) as novel energy storage solutions. The cell concept comprises a sodium metal anode, a tape-cast Na3.4Zr2Si2.4P0.6O12 solid electrolyte, and a Na3V2(PO4)3 cathode with liquid electrolyte. The impact of the Na3.4Zr2Si2.4P0.6O12 separator and sodium electrode on total cell resistance is evaluated in symmetric Na| Na3.4Zr2Si2.4P0.6O12|Na cells, demonstrating an ultra-low Ohmic resistance below 10 Ωcm2. The Na-aSSB achieved (85 ± 1) 239 ± 10) Wh/l at the cell level, among the highest reported for similar concepts. Cycling stability shows a Coulombic efficiency exceeding 990 cycles at a 2-h discharge rate. Five performance-limiting factors were identified: initial cathode resistance, degrading cell resistance during cycling, insufficient mechanical strength of the separator, dendrite formation, and non-optimized energy density. Suggested approaches to address these limitations highlight the technological potential of Na-aSSBs.

Details

Original languageEnglish
Article number2560836
Number of pages18
JournalMaterials Technology: Advanced Performance Materials
Volume40
Issue number1
Publication statusPublished - 18 Sept 2025
Peer-reviewedYes

External IDs

Scopus 105016536441

Keywords

Keywords

  • Almost-solid-state battery, NaZrSiPO, sodium battery, sodium metal electrode, solid electrolyte, tape casting, Na Zr Si P O