Excitons in ultrathin organic-inorganic perovskite crystals

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • Omer Yaffe - , Columbia University (Author)
  • Alexey Chernikov - , Columbia University (Author)
  • Zachariah M. Norman - , Columbia University (Author)
  • Yu Zhong - , Columbia University (Author)
  • Ajanthkrishna Velauthapillai - , Columbia University (Author)
  • Arend Van Der Zande - , Columbia University (Author)
  • Jonathan S. Owen - , Columbia University (Author)
  • Tony F. Heinz - , Stanford University, Stanford Linear Accelerator Center (SLAC) (Author)

Abstract

We demonstrate the formation of large sheets of layered organic-inorganic perovskite (OIPC) crystals, as thin as a single unit cell, prepared by mechanical exfoliation. The resulting two-dimensional OIPC nanosheets of 2.4 nm thickness are direct semiconductors with an optical band gap of 2.4 eV. They exhibit unusually strong light-matter interaction with an optical absorption as high as 25% at the main excitonic resonance, as well as bright photoluminescence. We extract an exciton binding energy of 490 meV from measurement of the series of excited exciton states. The properties of the excitons are shown to be strongly influenced by the changes in the dielectric surroundings. The environmental sensitivity of these ultrathin OIPC sheets is further reflected in the strong suppression of a thermally driven phase transition present in the bulk crystals.

Details

Original languageEnglish
Article number045414
JournalPhysical Review B - Condensed Matter and Materials Physics
Volume92
Issue number4
Publication statusPublished - 14 Jul 2015
Peer-reviewedYes
Externally publishedYes