Excitons at the Phase Transition of 2D Hybrid Perovskites

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • Jonas D. Ziegler - , Chair of Ultrafast Microscopy and Photonics (ct.qmat), University of Regensburg (Author)
  • Kai Qiang Lin - , University of Regensburg (Author)
  • Barbara Meisinger - , University of Regensburg (Author)
  • Xiangzhou Zhu - , Technical University of Munich (Author)
  • Manuel Kober-Czerny - , University of Oxford (Author)
  • Pabitra K. Nayak - , University of Oxford, Tata Institute of Fundamental Research (Author)
  • Cecilia Vona - , Humboldt University of Berlin (Author)
  • Takashi Taniguchi - , National Institute for Materials Science Tsukuba (Author)
  • Kenji Watanabe - , National Institute for Materials Science Tsukuba (Author)
  • Claudia Draxl - , Humboldt University of Berlin (Author)
  • Henry J. Snaith - , University of Oxford (Author)
  • John M. Lupton - , University of Regensburg (Author)
  • David A. Egger - , Technical University of Munich (Author)
  • Alexey Chernikov - , Chair of Ultrafast Microscopy and Photonics (ct.qmat), Clusters of Excellence ct.qmat: Complexity and Topology in Quantum Matter, University of Regensburg (Author)

Abstract

2D halide perovskites are among intensely studied materials platforms profiting from solution-based growth and chemical flexibility. They feature exceptionally strong interactions among electronic, optical, as well as vibrational excitations and hold a great potential for future optoelectronic applications. A key feature for these materials is the occurrence of structural phase transitions that can impact their functional properties, including the electronic band gap and optical response dominated by excitons. However, to what extent the phase transitions in 2D perovskites alter the fundamental exciton properties remains barely explored so far. Here, we study the influence of the phase transition on both exciton binding energy and exciton diffusion, demonstrating their robust nature across the phase transition. These findings are unexpected in view of the associated substantial changes of the free carrier masses, strongly contrast broadly considered effective mass and drift-diffusion transport mechanisms, highlighting the unusual nature of excitons in 2D perovskites.

Details

Original languageEnglish
Pages (from-to)3609-3616
Number of pages8
JournalACS photonics
Volume9
Issue number11
Publication statusPublished - 16 Nov 2022
Peer-reviewedYes