Excitation spectrum and spin Hamiltonian of the frustrated quantum Ising magnet Pr3BWO9
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Contributors
Abstract
We present a thorough experimental investigation on single crystals of the rare-earth based frustrated quantum antiferromagnet Pr3BWO9, a purported spin-liquid candidate on the breathing kagome lattice. This material possesses a disordered ground state with an unusual excitation spectrum involving a coexistence of sharp spin waves and broad continuum excitations. Nevertheless, we show through a combination of thermodynamic, magnetometric, and spectroscopic probes with detailed theoretical modeling that it should be understood in a completely different framework. The crystal field splits the lowest quasidoublet states into two singlets moderately coupled through frustrated superexchange, resulting in a simple effective Hamiltonian of an Ising model in a transverse magnetic field. While our neutron spectroscopy data do point to significant correlations within the kagome planes, the dominant interactions are out-of-plane, forming frustrated triangular spin-tubes through two competing ferro-antiferromagnetic bonds. The resulting ground state is a simple quantum paramagnet, where the presence of strongly hyperfine-coupled nuclear moments and weak structural disorder causes significant modifications to both thermodynamic and dynamic properties.
Details
Original language | English |
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Article number | 023267 |
Journal | Physical Review Research |
Volume | 6 |
Issue number | 2 |
Publication status | Published - Apr 2024 |
Peer-reviewed | Yes |