Exact open quantum system dynamics: Optimal frequency vs time representation of bath correlations

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

Abstract

Two different numerically exact methods for open quantum system dynamics, the hierarchy of pure states (HOPS) method, and the multi-Davydov-Ansatz are discussed. We focus on the suitability of the underlying representations of bath correlations. While in the HOPS case the correct description of the bath correlation function (BCF) in the time domain is decisive, it turns out that a windowed Fourier transform of the BCF is an appropriate indicator of the quality of the discretization in the multi-Davydov-Ansatz. For the spin-boson model with sub-Ohmic spectral density considered here, a discretization of the spectral density based on an exponential distribution, used previously, turns out to be most favorable.

Details

Original languageEnglish
Article number234105
Number of pages15
JournalJournal of Chemical Physics
Volume150
Issue number23
Publication statusPublished - 21 Jun 2019
Peer-reviewedYes

External IDs

Scopus 85067515343
ORCID /0000-0002-7806-3525/work/142234175
ORCID /0000-0002-8967-6183/work/142250863

Keywords

Keywords

  • EQUATIONS, EVOLUTION, ANSATZ