Enhancement of Exciton-Phonon Scattering from Monolayer to Bilayer WS2

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • Archana Raja - , Kavli Energy NanoScience Institute (ENSI), Stanford University (Author)
  • Malte Selig - , Technical University of Berlin (Author)
  • Gunnar Berghaüser - , Chalmers University of Technology (Author)
  • Jaeeun Yu - , Columbia University (Author)
  • Heather M. Hill - , Stanford University, Columbia University (Author)
  • Albert F. Rigosi - , Stanford University, Columbia University (Author)
  • Louis E. Brus - , Columbia University (Author)
  • Andreas Knorr - , Technical University of Berlin (Author)
  • Tony F. Heinz - , Stanford University, Stanford Linear Accelerator Center (SLAC) (Author)
  • Ermin Malic - , Chalmers University of Technology (Author)
  • Alexey Chernikov - , University of Regensburg (Author)

Abstract

Layered transition metal dichalcogenides exhibit the emergence of a direct bandgap at the monolayer limit along with pronounced excitonic effects. In these materials, interaction with phonons is the dominant mechanism that limits the exciton coherence lifetime. Exciton-phonon interaction also facilitates energy and momentum relaxation, and influences exciton diffusion under most experimental conditions. However, the fundamental changes in the exciton-phonon interaction are not well understood as the material undergoes the transition from a direct to an indirect bandgap semiconductor. Here, we address this question through optical spectroscopy and microscopic theory. In the experiment, we study room-temperature statistics of the exciton line width for a large number of mono- A nd bilayer WS2 samples. We observe a systematic increase in the room-temperature line width of the bilayer compared to the monolayer of 50 meV, corresponding to an additional scattering rate of â0.1 fs-1. We further address both phonon emission and absorption processes by examining the temperature dependence of the width of the exciton resonances. Using a theoretical approach based on many-body formalism, we are able to explain the experimental results and establish a microscopic framework for exciton-phonon interactions that can be applied to naturally occurring and artificially prepared multilayer structures.

Details

Original languageEnglish
Pages (from-to)6135-6143
Number of pages9
JournalNano letters
Volume18
Issue number10
Publication statusPublished - 10 Oct 2018
Peer-reviewedYes
Externally publishedYes

External IDs

PubMed 30096239

Keywords

Keywords

  • 2D materials, excitons, excitonâ'phonon interaction, scattering lifetime