Enhancement of Exciton-Phonon Scattering from Monolayer to Bilayer WS2
Research output: Contribution to journal › Research article › Contributed › peer-review
Contributors
Abstract
Layered transition metal dichalcogenides exhibit the emergence of a direct bandgap at the monolayer limit along with pronounced excitonic effects. In these materials, interaction with phonons is the dominant mechanism that limits the exciton coherence lifetime. Exciton-phonon interaction also facilitates energy and momentum relaxation, and influences exciton diffusion under most experimental conditions. However, the fundamental changes in the exciton-phonon interaction are not well understood as the material undergoes the transition from a direct to an indirect bandgap semiconductor. Here, we address this question through optical spectroscopy and microscopic theory. In the experiment, we study room-temperature statistics of the exciton line width for a large number of mono- A nd bilayer WS2 samples. We observe a systematic increase in the room-temperature line width of the bilayer compared to the monolayer of 50 meV, corresponding to an additional scattering rate of â0.1 fs-1. We further address both phonon emission and absorption processes by examining the temperature dependence of the width of the exciton resonances. Using a theoretical approach based on many-body formalism, we are able to explain the experimental results and establish a microscopic framework for exciton-phonon interactions that can be applied to naturally occurring and artificially prepared multilayer structures.
Details
Original language | English |
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Pages (from-to) | 6135-6143 |
Number of pages | 9 |
Journal | Nano letters |
Volume | 18 |
Issue number | 10 |
Publication status | Published - 10 Oct 2018 |
Peer-reviewed | Yes |
Externally published | Yes |
External IDs
PubMed | 30096239 |
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Keywords
ASJC Scopus subject areas
Keywords
- 2D materials, excitons, excitonâ'phonon interaction, scattering lifetime