Engineered coalescence by annealing 3D Ge microstructures into high-quality suspended layers on Si

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

Abstract

The move from dimensional to functional scaling in microelectronics has led to renewed interest toward integration of Ge on Si. In this work, simulation-driven experiments leading to high-quality suspended Ge films on Si pillars are reported. Starting from an array of micrometric Ge crystals, the film is obtained by exploiting their temperature-driven coalescence across nanometric gaps. The merging process is simulated by means of a suitable surface-diffusion model within a phase-field approach. The successful comparison between experimental and simulated data demonstrates that the morphological evolution is driven purely by the lowering of surface-curvature gradients. This allows for fine control over the final morphology to be attained. At fixed annealing time and temperature, perfectly merged films are obtained from Ge crystals grown at low temperature (450 degrees C), whereas some void regions still persist for crystals grown at higher temperature (500 degrees C) due to their different initial morphology. The latter condition, however, looks very promising for possible applications. Indeed, scanning tunneling electron microscopy and high-resolution transmission electron microscopy analyses show that, at least during the first stages of merging, the developing film is free from threading dislocations. The present findings, thus, introduce a promising path to integrate Ge layers on Si with a low dislocation density.

Details

Original languageEnglish
Pages (from-to)19219-19225
Number of pages7
JournalACS applied materials & interfaces
Volume7
Issue number34
Publication statusPublished - 2015
Peer-reviewedYes

External IDs

Scopus 84940834493
ORCID /0000-0002-4217-0951/work/142237378

Keywords

Keywords

  • heteroepitaxy, surface diffusion, semiconductors, substrate patterning, dislocations