Electron-electron correlation in graphite: A combined angle-resolved photoemission and first-principles study

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • A. Grueneis - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • C. Attaccalite - , Université de Lille (Author)
  • T. Pichler - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • V. Zabolotnyy - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • H. Shiozawa - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • S. L. Molodtsov - , TUD Dresden University of Technology (Author)
  • D. Inosov - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • A. Koitzsch - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • M. Knupfer - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • J. Schiessling - , Uppsala University (Author)
  • R. Follath - , Helmholtz Centre Berlin for Materials and Energy (Author)
  • R. Weber - , Helmholtz Centre Berlin for Materials and Energy (Author)
  • P. Rudolf - , University of Groningen (Author)
  • L. Wirtz - , Université de Lille (Author)
  • A. Rubio - , University of the Basque Country (Author)

Abstract

The full three-dimensional dispersion of the pi bands, Fermi velocities, and effective masses are measured with angle-resolved photoemission spectroscopy and compared to first-principles calculations. The band structure by density-functional theory underestimates the slope of the bands and the trigonal warping effect. Including electron-electron correlation on the level of the GW approximation, however, yields remarkable improvement in the vicinity of the Fermi level. This demonstrates the breakdown of the independent electron picture in semimetallic graphite and points toward a pronounced role of electron correlation for the interpretation of transport experiments and double-resonant Raman scattering for a wide range of carbon based materials.

Details

Original languageEnglish
Article number037601
Number of pages4
JournalPhysical review letters
Volume100
Issue number3
Publication statusPublished - 25 Jan 2008
Peer-reviewedYes
Externally publishedYes

External IDs

Scopus 38549135180

Keywords

Keywords

  • INTERCALATION COMPOUNDS, GRAPHENE

Library keywords