Electrically conductive and piezoresistive polymer nanocomposites using multiwalled carbon nanotubes in a flexible copolyester: Spectroscopic, morphological, mechanical and electrical properties

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • Kedar Nath Dhakal - , Tribhuvan University, Leibniz Institute of Polymer Research Dresden, Nepal Polymer Institute (Author)
  • Santosh Khanal - , Tribhuvan University (Author)
  • Beate Krause - , Leibniz Institute of Polymer Research Dresden (Author)
  • Ralf Lach - , Polymer Service GmbH Merseburg (Author)
  • Wolfgang Grellmann - , Polymer Service GmbH Merseburg (Author)
  • Hai Hong Le - , Leibniz Institute of Polymer Research Dresden (Author)
  • Amit Das - , Leibniz Institute of Polymer Research Dresden (Author)
  • Sven Wießner - , Chair of Elastomeric Materials (also: Head of the Department of Elastomers at the Leibniz-Institut für Polymerforschung Dresden e.V. (IPF)), Leibniz Institute of Polymer Research Dresden (Author)
  • Gert Heinrich - , Chair of Textile Technology, Leibniz Institute of Polymer Research Dresden (Author)
  • Jürgen Pionteck - , Leibniz Institute of Polymer Research Dresden (Author)
  • Rameshwar Adhikari - , Tribhuvan University, Nepal Polymer Institute (Author)

Abstract

Nanocomposites of multiwalled carbon nanotubes (MWCNTs) with poly(butylene adipate-co-terephthalate) (PBAT), a flexible aromatic–aliphatic copolyester, were prepared by melt mixing followed by compression moulding to investigate their spectroscopic, morphological, mechanical and electrical properties. A comparison of the Fourier transform infrared (FTIR) spectra of the neat polymer matrix and the composites showed no difference, implying a physical mixing of the matrix and the filler. A morphological investigation revealed the formation of a continuous and interconnected MWCNT network embedded in the polymer matrix with partial agglomeration. Increasing Martens hardness and indentation modulus and decreasing maximum indentation depth with increasing filler concentration demonstrated the reinforcement of the polymer by the MWCNTs. A volume resistivity of 4.6 × 105 Ω cm of the materials was achieved by the incorporation of only 1 wt.-% of the MWCNTs, which confirmed a quite low percolation threshold (below 1 wt.-%) of the nanocomposites. The electrical volume resistivity of the flexible nanocomposites was achieved up to 1.6 × 102 Ω cm, depending on the filler content. The elongation at the break of the nanocomposites at 374% and the maximum relative resistance changes (ΔR/R0) of 20 and 200 at 0.9 and 7.5% strains, respectively, were recorded in the nanocomposites (3 wt.-% MWCNTs) within the estimated volume resistivity range. A cyclic strain experiment shows the most stable and reproducible ΔR/R0 values in the 2%–5% strain range. The electrical conductivity and piezoresistivity of the investigated nanocomposites in correlation with the mechanical properties and observed morphology make them applicable for low-strain deformation-sensing.

Details

Original languageEnglish
Article number100806
JournalNano-Structures and Nano-Objects
Volume29
Publication statusPublished - Feb 2022
Peer-reviewedYes

External IDs

ORCID /0000-0003-0967-4557/work/173054849

Keywords

Keywords

  • Electrical conductivity, Piezoresistivity, Polymer nanocomposites, Strain-sensing, Volume resistivity