Elastic Softening in Synthetic Diamonds

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Contributors

  • Tatsuya Yanagisawa - , Hokkaido University (Author)
  • Ruo Hibino - , Hokkaido University (Author)
  • Hiroyuki Hidaka - , Hokkaido University (Author)
  • Hiroshi Amitsuka - , Hokkaido University (Author)
  • Toshiyuki Tashima - , Kyoto University (Author)
  • Mitsuhiro Akatsu - , Niigata University (Author)
  • Yuichi Nemoto - , Niigata University (Author)
  • Sergei Zherlitsyn - , Helmholtz-Zentrum Dresden-Rossendorf (HZDR) (Author)
  • Joachim Wosnitza - , Clusters of Excellence ct.qmat: Complexity and Topology in Quantum Matter, Chair of Physics of High Magnetic Fields, Helmholtz-Zentrum Dresden-Rossendorf (HZDR) (Author)

Abstract

This study reveals a previously unreported phenomenon: elastic softening in synthetic diamonds at temperatures below 1 K. We present ultrasonic measurements on single-crystalline, non-irradiated synthetic diamonds — specifically, type-IIa (colorless) and type-Ib (yellow) samples grown by high-pressure high-temperature (HPHT) synthesis, as well as type-IIa diamonds grown by chemical vapor deposition (CVD). A pronounced, divergent decrease in the elastic stiffness constant C44 was observed in all samples down to 20 mK. We attribute this softening to electric quadrupolar degrees of freedom with an irreducible representation T2 in the diamonds. However, the microscopic origin of this effect remains unclear. Drawing an analogy to behavior observed in silicon, we suggest the presence of an as-yet-unidentified, defect-derived quantum ground state with T1 or T2 symmetry, present at ppb-level concentrations in all three diamonds studied.

Details

Original languageEnglish
Article number073602
JournalJournal of the Physical Society of Japan
Volume94
Issue number7
Publication statusPublished - 15 Jul 2025
Peer-reviewedYes

Keywords

ASJC Scopus subject areas