Efficient Near-Infrared Light-Emitting Diodes Based on CdHgSe Nanoplatelets

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • Anatol Prudnikau - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • Hossein Roshan - , Italian Institute of Technology (Author)
  • Fabian Paulus - , Center for Advancing Electronics Dresden (cfaed), Leibniz Institute for Solid State and Materials Research Dresden, TUD Dresden University of Technology (Author)
  • Beatriz Martín-García - , CIC nanoGUNE, Ikerbasque Basque Foundation for Science (Author)
  • René Hübner - , Helmholtz-Zentrum Dresden-Rossendorf (Author)
  • Houman Bahmani Jalali - , Italian Institute of Technology (Author)
  • Manuela De Franco - , Italian Institute of Technology, University of Genoa (Author)
  • Mirko Prato - , Italian Institute of Technology (Author)
  • Francesco Di Stasio - , Italian Institute of Technology (Author)
  • Vladimir Lesnyak - , Chair of Physical Chemistry, TUD Dresden University of Technology (Author)

Abstract

Cadmium mercury selenide (CdHgSe) nanocrystals exhibit a unique combination of low-energy optical absorption and emission, which can be tuned from the visible to the infrared range through both quantum confinement and adjustment of their composition. Owing to this advantage, such nanocrystals have been studied as a promising narrow-band infrared light emitter. However, the electroluminescence of CdHgSe-based nanocrystals has remained largely unexplored, despite their potential for emitting light in the telecom wavelength range. Further benefits to their optical properties are expected from their shape control, in particular the formation of 2D nanocrystals, as well as from a proper design of their heterostructures. In this work, a colloidal synthesis of CdHgSe/ZnCdS core/shell nanoplatelets (NPLs) starting from CdSe template NPLs employing a cation exchange strategy is developed. The heterostructures synthesized exhibit photoluminescence that can be tuned from ≈1300 to 1500 nm. These near-infrared-active NPLs are employed in light-emitting diodes, demonstrating low turn-on voltage and high external quantum efficiency.

Details

Original languageEnglish
Article number2310067
JournalAdvanced functional materials
Volume34
Issue number8
Publication statusPublished - 19 Feb 2024
Peer-reviewedYes

Keywords

Keywords

  • cadmium mercury selenide-based nanoplatelets, colloidal semiconductor nanocrystals, efficient light emitting diodes, near infrared photoluminescence, telecommunication windows