Dithienylethene-Based Single Molecular Photothermal Linear Actuator
Research output: Contribution to journal › Research article › Contributed › peer-review
Contributors
Abstract
By employing a mechanically controllable break junction technique, we have realized an ideal single molecular linear actuator based on dithienylethene (DTE) based molecular architecture, which undergoes reversible photothermal isomerization when subjected to UV irradiation under ambient conditions. As a result, open form (compressed, UV OFF) and closed form (elongated, UV ON) of dithienylethene-based molecular junctions are achieved. Interestingly, the mechanical actuation is achieved without changing the conductance of the molecular junction around the Fermi level over several cycles, which is an essential property required for an ideal single molecular actuator. Our study demonstrates a unique example of achieving a perfect balance between tunneling width and barrier height change upon photothermal isomerization, resulting in no change in conductance but a change in the molecular length, which results in mechanical actuation at the single molecular level.
Details
Original language | English |
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Article number | e202218767 |
Number of pages | 8 |
Journal | Angewandte Chemie : a journal of the Gesellschaft Deutscher Chemiker ; International edition |
Volume | 62 |
Issue number | 16 |
Early online date | 8 Feb 2023 |
Publication status | Published - 11 Apr 2023 |
Peer-reviewed | Yes |
External IDs
unpaywall | 10.1002/anie.202218767 |
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Scopus | 85149323238 |
Mendeley | 8da71b3e-7f39-3cda-8dd6-b405f4ad0d91 |
PubMed | 36752105 |
ORCID | /0000-0001-8121-8041/work/142240863 |
Keywords
Research priority areas of TU Dresden
DFG Classification of Subject Areas according to Review Boards
- Theoretical Chemistry: Molecules, Materials, Surfaces
- Theoretical Chemistry: Electron Structure, Dynamics, Simulation
- Theoretical Condensed Matter Physics
- Computer-aided Material Design and Simulation of Material Behaviour from Atomistic to Microscopic Scale
- Synthesis and Properties of Functional Materials
- Experimental Condensed Matter Physics
Subject groups, research areas, subject areas according to Destatis
Sustainable Development Goals
ASJC Scopus subject areas
Keywords
- Break Junction, Molecular Machine, Molecular Switch, Photothermal Switching, Single Molecular Actuator