Disclosing magnetic clusters in the metallic half-Heusler ferromagnet Cr4PtGa17 with a breathing pyrochlore lattice

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

  • Y. Senyk - , Leibniz Institute for Solid State and Materials Research Dresden, TUD Dresden University of Technology (Author)
  • J. J. Abraham - , Chair of Experimental Solid State Physics, Leibniz Institute for Solid State and Materials Research Dresden, TUD Dresden University of Technology (Author)
  • A. Kanak - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • M. Horiacha - , Leibniz Institute for Solid State and Materials Research Dresden, Ivan Franko National University of L'viv (Author)
  • B. Büchner - , Clusters of Excellence ct.qmat: Complexity and Topology in Quantum Matter, Chair of Experimental Solid State Physics, Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • S. Wurmehl - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • V. Kataev - , Leibniz Institute for Solid State and Materials Research Dresden (Author)
  • A. Alfonsov - , Leibniz Institute for Solid State and Materials Research Dresden (Author)

Abstract

We report a ferromagnetic resonance (FMR) study of a single crystal of Cr4PtGa17, the first material of a half-Heusler (HH) type with a metallic ferromagnetic breathing pyrochlore structure. The spatial distribution of the magnetic free energy density derived from the FMR data appears to be of a cubic symmetry despite the lower symmetry coordination of magnetic Cr ions. This surprising finding strongly suggests that the Cr4Ga14 structural unit at the Y site of the HH general XYZ formula forms an octahedrally shaped integral magnetic cluster, likely due to strong exchange interaction between the Cr ions via covalent Cr-Ga-Cr bonds. The presence of magnetic clusters within a regular metallic lattice appears to be a new intriguing characteristics of these novel types of HH compounds whereas Cr4PtGa17, at the same time, constitutes the rare example of such metallic pyrochlore-type material.

Details

Original languageEnglish
Article number175826
JournalJournal of alloys and compounds
Volume1004
Publication statusPublished - 5 Nov 2024
Peer-reviewedYes

Keywords

Keywords

  • Breathing pyrochlore, Ferromagnetic resonance, Half-Heusler, Magnetic anisotropy, Magnetic cluster