Dielectrophoretic Growth of Platinum Nanowires: Concentration and Temperature Dependence of the Growth Velocity
Research output: Contribution to journal › Research article › Contributed › peer-review
Contributors
Abstract
The growth velocity of platinum nanowires in an aqueous solution of K2PtCl4 is investigated as a function of the metal complex concentration and temperature. The solution is specially prepared to provide mainly the neutral complex cis-[PtCl2(H2O)(2)] for growing nanowires by dielectrophoresis. The measured growth velocities indicate diffusion-limited nanowire growth at low concentration and high temperature in qualitative agreement with a theoretical analysis that includes the diffusion of metal complexes and the dielectrophoretic force on the complexes. At concentrations greater than 100 mu M and low temperature, different behavior is observed, suggesting the growth rate to be limited by the deposition reaction of platinum at the nanowire tip. The enhancement of the K+ concentration is found to support nanowire growth. Possible reasons for a rate limitation and for the difference between observed and calculated nanowire growth velocities are discussed.
Details
| Original language | English |
|---|---|
| Pages (from-to) | 7498-7504 |
| Number of pages | 7 |
| Journal | Langmuir |
| Volume | 28 |
| Issue number | 19 |
| Publication status | Published - 15 May 2012 |
| Peer-reviewed | Yes |
External IDs
| WOS | 000303969000023 |
|---|---|
| PubMed | 22509843 |
| Scopus | 84861123070 |
| ORCID | /0000-0002-6574-7848/work/211720304 |
Keywords
Keywords
- Metallic nanowires, Electron-transfer, Viscosity, Complexes, Kinetics, Cations, Chloro, Ion