Dielectrophoretic Growth of Platinum Nanowires: Concentration and Temperature Dependence of the Growth Velocity
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Contributors
Abstract
The growth velocity of platinum nanowires in an aqueous solution of K2PtCl4 is investigated as a function of the metal complex concentration and temperature. The solution is specially prepared to provide mainly the neutral complex cis-[PtCl2(H2O)(2)] for growing nanowires by dielectrophoresis. The measured growth velocities indicate diffusion-limited nanowire growth at low concentration and high temperature in qualitative agreement with a theoretical analysis that includes the diffusion of metal complexes and the dielectrophoretic force on the complexes. At concentrations greater than 100 mu M and low temperature, different behavior is observed, suggesting the growth rate to be limited by the deposition reaction of platinum at the nanowire tip. The enhancement of the K+ concentration is found to support nanowire growth. Possible reasons for a rate limitation and for the difference between observed and calculated nanowire growth velocities are discussed.
Details
Original language | English |
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Pages (from-to) | 7498-7504 |
Number of pages | 7 |
Journal | Langmuir |
Volume | 28 |
Issue number | 19 |
Publication status | Published - 15 May 2012 |
Peer-reviewed | Yes |
External IDs
WOS | 000303969000023 |
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PubMed | 22509843 |
Scopus | 84861123070 |
Keywords
Keywords
- Metallic nanowires, Electron-transfer, Viscosity, Complexes, Kinetics, Cations, Chloro, Ion