Dielectrophoretic Growth of Platinum Nanowires: Concentration and Temperature Dependence of the Growth Velocity

Research output: Contribution to journalResearch articleContributedpeer-review

Contributors

Abstract

The growth velocity of platinum nanowires in an aqueous solution of K2PtCl4 is investigated as a function of the metal complex concentration and temperature. The solution is specially prepared to provide mainly the neutral complex cis-[PtCl2(H2O)(2)] for growing nanowires by dielectrophoresis. The measured growth velocities indicate diffusion-limited nanowire growth at low concentration and high temperature in qualitative agreement with a theoretical analysis that includes the diffusion of metal complexes and the dielectrophoretic force on the complexes. At concentrations greater than 100 mu M and low temperature, different behavior is observed, suggesting the growth rate to be limited by the deposition reaction of platinum at the nanowire tip. The enhancement of the K+ concentration is found to support nanowire growth. Possible reasons for a rate limitation and for the difference between observed and calculated nanowire growth velocities are discussed.

Details

Original languageEnglish
Pages (from-to)7498-7504
Number of pages7
JournalLangmuir
Volume28
Issue number19
Publication statusPublished - 15 May 2012
Peer-reviewedYes

External IDs

WOS 000303969000023
PubMed 22509843
Scopus 84861123070

Keywords

Keywords

  • Metallic nanowires, Electron-transfer, Viscosity, Complexes, Kinetics, Cations, Chloro, Ion